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467-MOF(Al)

467-MOF(Al)

【Numbering】BK2021013017 【CAS】1818266-93-1
【Item No.】 【specification】
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Material name: 467-MOF
Other name: Al-bttotb; [Al3(BTTB)2(OH)3](DMF)5.5(H2O)3
CAS: 1818266-93-1
Structure information
Unit molecular formula C54H30O21Al3.C3H7NO Unit molecular weight 1168.84168
Coordination metal Al ligand 4,4',4''-(phenyl-1,3,5-trioxo)-benzoic acid (CAS: 1071125-59-1)
Aperture Two-dimensional vertical channel: 0.4*0.5 and 0.5*0.6 Pore volume 0.46 cm3/g
Specific surface BET specific surface 700 m2/g

Analog structure

Product traits
Product morphology, colorless grains
Colorless Crystals
Particle size
stability
1) 467-MOF / Al-bttotb is very stable in nature, it can be stable for more than 1 week in the air at a high temperature of 150 degrees; the thermal decomposition temperature is greater than 350 degrees.
2) 467-MOF / Al-bttotb is stable for more than 24 hours in water, acid and weak alkaline environment (PH 1-11), stable in boiling water for several days, stable in common organic solvents (such as DMF, THF, ethanol, etc.)
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 120 degrees (vacuum) for 6 hours before use
Other features
Fluorescence: NA
Application field
1) 467-MOF can be applied to gas and pollutant adsorption
2) 467-MOF/Al-bttotb has a stable microporous structure and can be used to separate various alkanes molecules [r2]
Characterization map

references
1) Z. Wang, M. Chen, C. Liu, X. Wang, H. Zhao, M. Du, Chem. Eur. J. 2015, 21, 17215–17219, DOI: 10.1002/chem.201502615
2) L. Yu, X. Dong, Q. Gong, S. Acharya, Y. Lin, H. Wang, Y. Han, T. Thonhauser, J. Li, J. Am. Chem. Soc. 2020, 142, 15, 6925-6929, DOI: 10.1021/jacs.0c01769


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