Cu(Qc)2
| 【Numbering】BK2021012807 | 【CAS】2381226-20-4 | ||
| 【Item No.】 | 【specification】 | ||
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Other names: Cu(Qc)2; [Cu(quinoline-5-carboxyate)2]; Qc-5Cu-sql
CAS: 2381226-20-4
Structure information
Unit molecular formula C20H12N2O4Cu Unit molecular weight 407.87
Coordination metal Cu ligand
Quinoline-5-carboxylic acid (CAS: 7250-53-5)
Aperture 3.3-3.8A Pore volume
Specific surface no nitrogen adsorption
Analog structure
Product traits
Product appearance: blue powder
White Powder
Irregular or diamond-shaped flakes with a particle size of 5-10um
stability
1) Cu(QcQc) is very stable, stable for months in air and water
2) Thermal decomposition temperature is about 240℃
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 120 degrees (vacuum) for 12 hours before use
Other features
Fluorescence: NA
Application field
1) Ultra-micro channels can be used for ethane/ethylene separation, CO2/N2 separation, etc.
2) The normalized channel of the pillar structure can be used for ion passage
Characterization map
references
1) Chen, Kai-Jie; Madden, David G.; Pham, Tony; Forrest, Katherine A.; Kumar, Amrit; Yang, Qing-Yuan; Xue, Wei; Space, Brian; Perry, John J. IV; Zhang , Jie-Peng; Chen, Xiao-Ming; Zaworotko, Michael J.; Angew. Chem., Int. Ed. 2016, 55(35), 10268-10272, DOI: 10.1002/anie.201603934; Tuning Pore Size in Square ‐Lattice Coordination Networks for Size‐Selective Sieving of CO2
2) Lin, Rui-Biao; Wu, Hui; Li, Libo; Tang, Xiao-Liang; Li, Zhiqiang; Gao, Junkuo; Cui, Hui; Zhou, Wei; Chen, Banglin; J. Am. Chem. Soc. 2018, 140, 40, 12940-12946, DOI: 10.1021/jacs.8b07563; Boosting Ethane/Ethylene Separation within Isoreticular Ultramicroporous Metal--Organic Frameworks
3) Tang, Yuning; Wang, Sa; Zhou, Xin; Wu, Ying; Xian, Shikai; Li, Zhong; Chem. Eng. Sci. 2020, 213, 115355, DOI: 10.1016/j.ces.2019.115355; Room temperature synthesis of Cu(Qc)2 and its application for ethane capture from light hydrocarbons
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