PCN-222(H)
| 【Numbering】BK2021012208 | 【CAS】1403461-06-2 | ||
| 【Item No.】 | 【specification】 | ||
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Material name: PCN-222(H)
Other name: MOF-545
CAS: 1403461-06-2
Structure information
Unit molecular formula C96H52N8O32Zr6 Unit molecular weight 2376.81848
Coordination metal Zr ligand 4-carboxyphenyl porphyrin (CAS: 14609-54-2)
Pore size 3.7nm; 1.3 nm Pore volume 1.5 cm3/g
Specific surface BET specific surface 2000 m2/g
Analog structure
Product traits
Product appearance dark purple powder
Dark Purple Powder
Particle size
2um*50nm needle-like crystal grain
200*20nm rod-shaped nanoparticles (can be used in cell experiments)
stability
1) PCN-222 is stable in air, stable in aqueous solution and acidic conditions (PH 1-11)
2) High thermal stability, thermal decomposition temperature is about 400℃
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 120 degrees (vacuum) for 10 hours before use
Other features
Fluorescence: excitation wavelength 413nm, emission wavelength 643nm
Application field
1) PCN-222 has stable one-dimensional pores, which can support metal catalysts or gas storage and adsorption materials
2) PCN-222 has large pores of 3.7nm, which can be used to adsorb embedded drug molecules and smaller molecular weight enzymes and peptides
3) PCN-222 (H or M) can convert oxygen into singlet oxygen under light conditions, has the performance of photocatalytic organic reaction, and can be used as a biological probe
Characterization map
references
1) D. Feng, Z.-Y. Gu, J.-R. Li, H.-L. Jiang, Z. Wei, and H.-C. Zhou, Angew. Chem. 2012, 124, 10453-10456, DOI: 10.1002/ange.201204475 ; Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
2) W. Morris, B. Volosskiy, S. Demir, F. Gándara, P. L. McGrier, H. Furukawa, D. Cascio, J. F. Stoddart, O. M. Yaghi, Inorg. Chem. 2012, 51, 6443-6445, DOI: 10.1021/ic300825s ; Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
| Warm tips: Suzhou Beike nano products are only used for scientific research, not for human body,different batches of products have different specifications and performance |
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